Answers
2.
(a) Mass of oxygen = Mass of magnesium oxide - Mass of magnesium = 20 g - 12 g = 8 g. [1 mark]
(b) The ratio of magnesium to oxygen by mass is 12 g : 8 g, which simplifies to 3:2. [2 marks]
(c) Using the ratio 3:2, if 24 g of magnesium reacts, the mass of oxygen required would be (2/3) * 24 g = 16 g. Since 16 g of oxygen is provided, all the magnesium will react. The mass of magnesium oxide formed will be 24 g (Mg) + 16 g (O) = 40 g. [2 marks]
3.
(i) Both A and R are true, and R is the correct explanation of A. [1 mark]
4.
(a) Barium sulfate (). [1 mark]
(b)
[2 marks]
(c) According to the Law of Conservation of Mass, total mass of reactants = total mass of products.
Mass of barium chloride = 10 g. Let the mass of sodium sulfate be 'x' and the mass of sodium chloride be 'y'.
.
From the balanced equation, the molar mass of is g/mol, and the molar mass of is g/mol.
If 10 g of reacts, it reacts with (10 g / 208.3 g/mol) * 142.0 g/mol (molar mass of ) of sodium sulfate.
However, we can use the mass conservation. The products are (11.6 g) and . The reactants are (10 g) and . The Law of Conservation of Mass states that mass of reactants = mass of products.
If 10 g of reacts with excess to form 11.6 g of , then the mass of produced can be calculated.
Let's assume complete reaction.
Mass of reactants = Mass of products
Mass of + Mass of = Mass of + Mass of
The question implies that reacts with excess . Thus, the limiting reactant is .
The mass of formed from 10 g of can be calculated using stoichiometry. Molar mass of = 208.3 g/mol. Molar mass of = 233.4 g/mol.
Mass of formed from 10 g = (10 g / 208.3 g/mol) * 233.4 g/mol = 11.2 g.
There seems to be a slight discrepancy in the given data (11.6 g precipitate). Assuming the precipitate mass of 11.6 g is correct and it is , and the reaction is complete.
Total mass of reactants = Total mass of products
Mass of (10g) + Mass of (excess) = Mass of (11.6g) + Mass of (y)
We need to find 'y'. To do this precisely, we need the mass of that reacted.
Let's re-evaluate using mass conservation directly. If 10 g of reacts to form 11.6 g of , this implies that some other reaction or impurity might be present.
However, if we strictly follow the law of conservation of mass for the given reaction and assume the question intends to test this:
Let's assume the mass of reacted is .
From the stoichiometry, 1 mole of produces 1 mole of .
Molar mass of = 208.3 g/mol. Molar mass of = 58.5 g/mol.
If 10 g of reacts, moles of = 10 / 208.3 = 0.048 mol.
Moles of formed = 0.048 mol.
Mass of = 0.048 mol * 58.5 g/mol = 2.8 g.
Total mass of products = Mass of + Mass of = 11.6 g + 2.8 g = 14.4 g.
Mass of reactants = Mass of + Mass of .
To verify mass conservation, we need the mass of that reacted.
Let's assume the provided precipitate mass (11.6 g) is correct and the reaction is .
If 10 g of reacts to produce 11.6 g of , then by mass conservation, the mass of reacted is , and the mass of produced is .
.
Using stoichiometry: Moles mol.
Moles formed = 0.048 mol. Mass of = 0.048 * 233.4 = 11.2 g.
This confirms there is a slight inconsistency in the problem data (11.6 g vs 11.2 g). Let's proceed with the given value of 11.6 g.
If 10 g reacts with excess , and forms 11.6 g .
Moles of formed = 11.6 g / 233.4 g/mol = 0.0497 mol.
This means moles of that reacted must be approximately 0.0497 mol.
Mass of reacted = 0.0497 mol * 208.3 g/mol = 10.35 g. (Slightly more than given, indicating inconsistency).
Let's assume the mass of is the limiting reactant and the mass of is given correctly.
If 10 g of reacts completely, moles of mol.
This produces 0.048 mol of . Mass of g.
Now, using mass conservation:
Mass of reactants = Mass of products
Mass of + Mass of = Mass of + Mass of
10 g + Mass of = 11.6 g + 2.8 g
Mass of = 11.6 g + 2.8 g - 10 g = 4.4 g.
This implies that only 4.4 g of was needed.
However, a simpler approach given the question's likely intent: If 10 g of reacts, and the total mass of products is 11.6 g of precipitate + mass of NaCl.
By Law of Conservation of Mass: Mass of + Mass of = Mass of + Mass of .
If we consider only the reaction of to form and , and use the given precipitate mass:
Let's assume 10 g of and excess react to form 11.6 g and g .
The law states mass is conserved. We need to relate the masses.
Using molar masses:
1 mole (208.3 g) gives 1 mole (233.4 g) and 2 moles (2 * 58.5 = 117 g).
Ratio of mass of to = 208.3 : 233.4.
Ratio of mass of to = 208.3 : 117.
If 10 g reacts:
Mass of formed = (233.4 / 208.3) * 10 g = 11.2 g. (This is the expected mass of precipitate).
If the precipitate is indeed 11.6 g, there's an issue. Let's proceed assuming the Law of Conservation of Mass should hold and we need to find the mass of NaCl.
Mass of (10g) + Mass of reacted = Mass of (11.6g) + Mass of (y).
If we assume that 10 g of completely reacts to form 11.6 g of , this implies a mass gain, which is impossible.
Let's assume the question is testing the basic idea: Mass of reactants = Mass of products.
If 10 g of reacts with some amount of to produce 11.6 g of and g of .
By conservation of mass, total mass of reactants = total mass of products.
We don't know the mass of used, but it is in excess.
Let's use the stoichiometry again, assuming the problem meant for the calculation to be possible.
If 10 g of reacts, moles = 0.048.
This should produce 0.048 mol of . Mass of g.
So, if 11.6 g of is formed, then by mass conservation:
Mass of reactants = 10 g () + Mass of
Mass of products = 11.6 g () + 2.8 g () = 14.4 g.
This implies that the mass of that reacted was 14.4 g - 10 g = 4.4 g.
This suggests that 10 g of reacts with 4.4 g of to give 11.6 g of and 2.8 g of .
Check: 10 + 4.4 = 14.4. 11.6 + 2.8 = 14.4. Mass is conserved.
So, the mass of sodium chloride produced is 2.8 g. [2 marks]
5.
(a) Ionic bond. [1 mark]
(b) P has 5 valence electrons. It needs 3 more electrons to complete its octet. So, it will tend to gain 3 electrons. [1 mark]
(c) Q has 7 valence electrons. It needs 1 more electron to complete its octet. So, it will tend to gain 1 electron. [1 mark]
(d) For ionic bond formation, P will form ion and Q will form ion. To balance the charges, we need 1 atom of P and 3 atoms of Q. Thus, the formula of the compound formed will be . [1 mark]
6.
(a) The Law of Conservation of Mass. [1 mark]
(b) In an open system, a gas is produced during the reaction (calcium carbonate with hydrochloric acid produces carbon dioxide gas). This gas escapes into the atmosphere, resulting in a decrease in the measured mass of the products. [2 marks]
7.
(a) Sodium chloride (NaCl). Ionic compounds are generally soluble in water and dissociate into ions, which can move freely to conduct electricity. [2 marks]
(b) Naphthalene. Covalent compounds like naphthalene are generally non-polar and soluble in non-polar solvents like kerosene, while being insoluble in polar solvents like water. [2 marks]
8.
(i) Both A and R are true, and R is the correct explanation of A. [1 mark]
9.
(a) The Law of Definite Proportions (or Law of Constant Proportions). [1 mark]
(b) Ratio of mass of hydrogen to oxygen = 2 g : 16 g = 1:8. [1 mark]
(c) Since water always contains hydrogen and oxygen in the mass ratio of 1:8:
For 54 g of water, mass of hydrogen = (1 / (1+8)) * 54 g = (1/9) * 54 g = 6 g.
Mass of oxygen = (8 / (1+8)) * 54 g = (8/9) * 54 g = 48 g. [2 marks]
10.
(a) Nitrogen (N): 2, 5. Hydrogen (H): 1. [1 mark]
(b) Nitrogen needs to gain or share 3 electrons to complete its octet. [1 mark]
(c) Each Hydrogen atom needs to gain or share 1 electron to complete its duplet. [1 mark]
(d) Three covalent bonds are formed in an ammonia molecule. The nitrogen atom shares one electron with each of the three hydrogen atoms, and each hydrogen atom shares its one electron with nitrogen. This forms three shared pairs of electrons, resulting in three single covalent bonds. [2 marks]
11.
(a) The Law of Conservation of Mass might appear to be violated because the initial mass of reactants (5 g + 10 g = 15 g) is greater than the final mass of the residue (12 g). [1 mark]
(b) In an open system, a gas is likely produced and escapes into the atmosphere. This loss of gaseous mass makes the measured mass of the solid residue less than the total mass of the reactants. [2 marks]
(c) If the reaction was carried out in a closed container, the gas would be trapped, and the total mass of the products (including the gas) would be equal to the total mass of the reactants, which is 15 g. [1 mark]
12.
(a) Element M has 2 valence electrons, so its valency is 2. [1 mark]
(b) It will form a cation with a +2 charge, i.e., . [1 mark]
(c) Element M forms ion and element X (with 7 valence electrons) forms ion. To balance the charges, we need one atom of M and two atoms of X. Thus, the formula of the compound formed will be . [2 marks]
13.
(i) Both A and R are true, and R is the correct explanation of A. [1 mark]
14.
(a)
[1 mark]
(b) According to the Law of Conservation of Mass, the total mass of reactants equals the total mass of products.
Mass of reactants = Mass of hydrogen + Mass of chlorine = 2 g + 71 g = 73 g.
Therefore, the mass of hydrochloric acid formed is 73 g. This demonstrates the Law of Conservation of Mass. [2 marks]
15.
(a) Phosphorus (P, atomic number 15): 2, 8, 5. Sulfur (S, atomic number 16): 2, 8, 6. [1 mark]
(b) Phosphorus has 5 valence electrons and needs 3 more to complete its octet, while Sulfur has 6 valence electrons and needs 2 more. Both elements are non-metals. They are likely to form covalent bonds by sharing electrons. [2 marks]
(c) Phosphorus and Sulfur can form compounds like , , . A simple possible formula based on sharing to achieve octets could be inferred, but without further information on the specific ratio of combination, it's difficult to give a single definitive formula. However, if we consider phosphorus forming and sulfur forming (simplification for reactivity), a ratio might emerge. A more common approach is to consider phosphorus forming and sulfur forming . Their reaction can lead to complex structures. If we consider a simplified approach where P needs 3 electrons and S needs 2, a ratio of 2 P to 3 S might be considered for sharing, leading to . Another approach: P shares its 3 electrons and S shares 2 electrons. This can lead to (4 P atoms sharing 3 electrons each and 3 S atoms sharing 2 electrons each). For this question, let's consider a common phosphorus sulfide, e.g., . (Note: This question might be challenging without specific context on which phosphorus sulfide. A simpler answer might be expected if they combine to form a simple covalent compound). A simpler interpretation of "combine" without specific structure could lead to considering valencies. Phosphorus typically has valency 3 or 5. Sulfur typically has valency 2. If P has valency 3 and S has valency 2, they form . [1 mark]
16.
(a) It is likely to be a covalent compound. [1 mark]
(b) The compound is soluble in water, which is a polar solvent. This suggests some polarity. However, it does not conduct electricity in solid state or in its aqueous solution. Non-ionic compounds do not conduct electricity. Ionic compounds conduct electricity when dissolved because their ions are free to move. Since it does not conduct electricity even when dissolved, it is unlikely to be ionic. Therefore, it is likely a covalent compound that might be soluble in water due to some polarity or hydrogen bonding. [2 marks]
17.
(a) Mass of oxygen reacted = Mass of carbon dioxide - Mass of carbon = 22 g - 6 g = 16 g. [1 mark]
(b) The ratio of carbon to oxygen by mass in carbon dioxide is 6 g : 16 g, which simplifies to 3:4. [2 marks]
(c) Since the ratio of carbon to oxygen is 3:4, if 10 g of carbon reacts, the mass of oxygen needed is (4/3) * 10 g = 13.33 g. The mass of carbon dioxide formed will be 10 g (carbon) + 13.33 g (oxygen) = 23.33 g. [1 mark]
18.
(a) Aluminium forms an aluminium ion () with a charge of +3. Oxygen forms an oxide ion () with a charge of -2. [1 mark]
(b) Al valency = 3, O valency = 2.
Criss-crossing the valencies:
The chemical formula for aluminium oxide is . [2 marks]
19.
(i) Both A and R are true, and R is the correct explanation of A. [1 mark]
20.
(a) Metal M has 1 valence electron, so it will tend to lose it to form a cation . Non-metal X has 6 valence electrons and needs 2 electrons to complete its octet, so it will tend to gain 2 electrons to form an anion . The bond formed between a metal and a non-metal by the transfer of electrons is an ionic bond. [1 mark]
(b) M forms ion and X forms ion. To balance the charges, we need two atoms of M and one atom of X. The formula of the compound formed will be . [2 marks]
(c) The compound formed is ionic (). Ionic compounds, when dissolved in water, dissociate into ions, which are free to move and can conduct electricity. Therefore, the aqueous solution of this compound will conduct electricity. [2 marks]